The new era hypothesis of coastal degradation: G(s) elements-gallium, gadolinium, and germanium.

Mining of precious metals contributes to environmental pollution, especially in coastal areas, and conventional treatment methods are not always effective in removing metal contaminants. Some of these metals, such as gadolinium, germanium and gallium, have caused increasing concern worldwide, as little is known about their current concentrations in the aquatic environment and their biological significance. Therefore, the aim of this study was to determine for the first time the variation of average G(s) concentrations (gallium, gadolinium and germanium) by month/season/site differences along the coast of Istanbul. The ecological risk index was calculated to assess the contamination of seawater and to serve as a diagnostic tool for the mitigation of water pollution. The average distribution G(s) in seawater was in the following order: Ga > Gd > Ge. In addition, the potential ecological risk in the sampling areas ranged from 68 to 1049. Of the three metals, Gd poses the highest ecological risk (grade III). In the spatial distribution of ecological risks, Gd mainly originated from discharges from wastewater treatment plants. Therefore, the sources of the anthropogenic Gd anomaly in wastewater should be identified, as this indicates the possibility of human exposure to potentially harmful anthropogenic compounds.

Potential Ecological Risk Assessment of Critical Raw Materials: Gallium, Gadolinium, and Germanium.

In recent years, the demand for critical raw materials such as gallium, gadolinium and germanium (G(s)) has steadily increased in various industries. However, treatment or recycling rates of these elements are extremely low, which can lead to environmental pollution. An assessment of the ecological risks was also not possible until now, as there were no calculated toxicity coefficients for G(s). In this study, a well-known method, the so-called potential ecological risk index (PERI), was used for the first time to calculate the toxicity coefficients of these elements using data from recent literature studies on G(s) elements. The toxicity coefficient of each of the three elements was determined as five (5). The results show that G(s) have the same toxicity coefficient as Cu and Pb and are higher than that of Cr. The ecological risk index results varied from 4 to 414, 0.98 to 25.98 and 2.50 to 284.64 for Ga, Gd and Ge, respectively. The results show that Ga and Ge pose high ecological risk while the Eri of Gd is low. The toxicity coefficients of these elements have been calculated for the first time in the literature and provide a practical use for calculating the potential ecological risk index.

Impact of coastal wastewater treatment plants on microplastic pollution in surface seawater and ecological risk assessment.

This study aims to understand the influence of wastewater treatment plant discharge on the microplastic status in the surface seawater of Istanbul. For this purpose, for the first time, the distribution, composition, and ecological risk of microplastics at nine sampling stations on the southern coast of Istanbul, Marmara, were investigated at monthly intervals over a one-year period. The results showed that the microplastic abundance ranged from 0 to over 1000 particles per liter. Fibers were the dominant form at all stations. Microplastics 249-100 µm were the dominant size, and transparency was the color most found at all stations. Polyethylene and ethylene-vinyl acetate were the major types of microplastics, accounting for 50% overall. The pollution load index revealed that over 70% of sampling stations were at hazard level I. However, the hazardous index was categorized as level III with a value of 662.3 due to the presence of the most hazardous polymer named polyurethane. Further investigations into the risk assessment of MP can reveal crucial knowledge for understanding the microplastic cycle.

Generic foresight model in changing hygiene habits with the pandemic: use of wet wipes in next generations.

The vast use of wet wipes has now become a habitude, particularly following the altered perception of cleanliness during the pandemic and the encouragement towards using WW (wet wipe) to ensure parent's and children's hygiene. This study primarily aims to create a projection of the WW waste that will emerge in Turkey as a result of the promoted consumption by children who are predicted to retain the WW usage practices of their parents. In line with this habit adopted by children, the number of daily WW usage which is currently around 210 million is expected to rise to over 250 million between the years 2040 and 2060, depending on how the children are guided by their parent's existing habits. In this study, related calculations were made with FT-IR spectroscopy, taking into account the functional bond structure and percentage distribution of polymers in WWs. In this way, it is detected that 360 T, 568 T, and 623 T polymer materials would be thrown into the environment per day in 2021, 2040 and 2060, respectively. The damage of chemicals in WW content, employed at various concentrations, to the ecosystem structure is predicted and measures to be taken are outlined.

Transgenerational effects of polyethylene microplastic fragments containing benzophenone-3 additive in Daphnia magna.

Maternal exposure to microplastics (MPs) plays an important role in the fitness of unexposed progeny. In this study, the transgenerational effects of polyethylene MP fragments (17.35 ± 5.50 µm) containing benzophenone-3 (BP-3; 2.85 ± 0.16% w/w) on chronic toxicity (21 d) in Daphnia magna were investigated across four generations. Only D. magna in the F0 generation was exposed to MP fragments, MP/BP-3 fragments, and BP-3 leachate to identify the transgenerational effect in the F3 generation. The mortality of D. magna induced by MP and MP/BP-3 fragments was recovered in the F3 generation, but somatic growth and reproduction significantly decreased compared to the control. Additionally, reproduction of D. magna exposed to BP-3 leachate significantly decreased in the F3 generation. These findings confirmed the transgenerational effects of MP fragment and BP-3 additive on D. magna. Particularly, the adverse effect on D. magna reproduction seemed to be cumulative across four generations for MP/BP-3 fragments, while it was an acclimation trend for BP-3 leachate. However, there was no significant difference in global DNA methylation in D. magna across four generations, thus requiring a gene-specific DNA methylation study to identify different epigenetic transgenerational inheritance.

Evaluation of Istanbul from the environmental components' perspective: what has changed during the pandemic?

This study aims to determine the 1-year change over the pandemic period in Istanbul, the megacity with the highest population in Turkey, based on environmental components. Among the environmental topics, water consumption habits, changes in air quality, changes due to noise elements, and most importantly, the changes in usage habits of disposable plastic materials that directly affect health have been revealed. The results obtained showed that, in Istanbul, 8.1 × 108 gloves should be considered waste, and considering the population living in districts along coastal areas, the number of waste masks that are likely to end up in the sea was 325.648 pieces/day. The results of the air quality and noise measurements during the pandemic showed that reductions in parallel with human activities were recorded with the lockdown effect. The average noise values of the districts along both sides of the Bosporus, where urbanization is concentrated, were between 50 and 59 dB. The precautions taken during the pandemic have had an effective role in reducing air pollution in Istanbul. In the measurements, the parameters with effective reductions were PM10 (7-47%), PM2.5 (13-48%), NO2 (13-38%), and SO2 (10-56%). As a result, Istanbul's year of changes during the pandemic period, in terms of water, air, noise, and solid plastic wastes, which are the most important components of the environment, is presented.

The spatial and temporal changes of beach litter on Istanbul (Turkey) beaches as measured by the clean-coast index.

Possible access routes of macro and mesoplastics, acting as the main sources of pollution in the coastal ecosystem, are examined as a case study on four beaches along the Istanbul coast. A total number of 3787 items belonging to 12 categories of debris types were collected as follows: macroplastics 47.8%; mesoplastics 9.2%; and others 43.0% such as paper pieces, glass pieces and metal beverage cans. Clean-coast and carbonyl indexes were also used to identify the level of cleanliness of the sampling sites. The clean-coast index revealed that all of the sample sites were categorized as extremely dirty. Moreover, carbonyl index results indicate that 35.7% of the samples were at a high oxidation level indicating that some of the particles relatively spend more time on beaches. The litter concentration and surface oxidation results were addressing issues that should be taken into consideration to improve litter management strategies of the beaches.

Comparison of metropolitan cities for mortality rates attributed to ambient air pollution using the AirQ model.

In the present study, the air pollution dynamics of the metropolitan cities of Balikesir, Bursa, Istanbul, Kocaeli, Sakarya and Tekirdag in the Marmara Region, which is the geographical region with the highest urban and industrial activity in Turkey, were examined for the time period between 2016 and 2019. Annual changes in the cities in terms of air pollution, which was examined with a focus on the PM2.5 parameter as indicated by United Nations (UN) Sustainable Development Goals (SDGs); differences in the cities by years; and the seasonal changes in air pollution in the cities were investigated. Additionally, mortality rates attributed to air pollution were calculated with the AirQ + software based on integrated exposure-response function recommended by the World Health Organization (WHO) and the UN using city-scale statistics of fatal disease cases that can be attributed to air pollution. It was determined that all cities in the Marmara Region study area exceeded the limit PM2.5 values specified by the European Union (EU) in the years 2016, 2017 and 2018 while only Kocaeli and Tekirdag were below the limit values in 2019. The limit values specified by the WHO were exceeded in all cities in each year. A total of 46,920 premature deaths attributed to the exceedance of WHO limit values were calculated for the years 2016, 2017, 2018 and 2019 with 11,895, 13,853, 11,748 and 9,429, respectively. Determining national limit values for the PM2.5 parameter, which is among the most important factors of air pollution, and monitoring it in a sustainable manner using a sufficient number of well-equipped stations is of great importance. This way, national, regional and urban action plans regarding the impact of air pollution on human health, as indicated by UN SDGs, can be prepared.

Temporal changes in water quality index of polluted lagoon ecosystems: a case study on the Küçükçekmece Lagoon.

For lagoon ecosystems, it is crucial to conduct long-term monitoring of the water quality parameters and predict their potential effects. This study aimed to analyse the changes in the water quality index (WQI) profile of the Küçükçekmece Lagoon in Istanbul, Turkey, which has been facing ecological problems, and determine the increased stress in aquatic biota due to different pollutants. To begin, the sampling data were obtained from the Küçükçekmece Lagoon throughout a 13-month period in 2018-2019. The estimated WQI values were compared to studies conducted in the same study area within the last 20 years. Then, the relationship between the acute toxicity of surface waters, which is the recommended parameter for analyses in this field, and the WQI was determined. Although the water class has generally been defined as 'good quality' (WQI = 86), the study found it to be 'very poor quality' (WQI = 112 and 97, respectively) with bloom events and toxicity effects in spring and autumn. When compared with the WQIs calculated from the last 20 years, a significant improvement in water quality at station L1 (decreased from WQI = 288 to WQI = 161) and a deterioration at station L2 (increased from WQI = 71 to WQI = 100) were observed. The acute toxicity and water quality classes were highly positively correlated (r = 0.773; p < 0.01). The method, used for the first time in this area, was able to interpret the acute toxicity of lagoon surface waters and WQI data. Furthermore, the use of this method was recommended for rapid analysis of the increased stress in aquatic biota.

Modelling of possible tanker accident oil spills in the Istanbul Strait in order to demonstrate the dispersion and toxic effects of oil pollution.

Countries located on the Black Sea coast perform most of their sea trade through the Istanbul Strait (IS). Approximately 50,000 ships pass through the IS each year, with crude oil tankers making up the majority. Thus, the aim of the study is to determine the acute toxic effect of oil pollution that may occur as a result of crude oil tanker accidents in the IS. By utilising data related to accidents that have occurred in the IS, locations of concentrated tanker accidents, or "hot spots," were determined by Kernel Density Analysis. Subsequently, the distribution of potential leaks following an oil tanker accident, within these hot spots, is modelled with GNOME software. Finally, acute toxicity caused by oil pollution in the marine ecosystem is determined by Aliivibrio fischeri luminescent bacteria toxicity test. In this research, 5 hot spots are identified, where the maximum calculated amount of oil that can reach the coastline after 72 h is 3096 metric tons. Similarly, oil pollution can affect a total coastline of 30-35 km. Furthermore, it was determined that after the oil was diluted in seawater, at a ratio of 1:200,000, the toxic effects decrease (EC50 above 100 mg/L), yet the chronic effects may still continue. The results of this study may serve as a reference for coastal state authorities to develop emergency response plans. Having this valuable knowledge of where high-risk accidents are most concentrated, where the accidents occur intensely, which areas can be affected by the pollution, the duration of the pollution effects, and the distance between the areas, will help determine the number of intervention stations to be installed, their locations, and equipment to be installed to the stations.

A comprehensive bibliometric overview: antibiotic resistance and Escherichia coli in natural water.

The environment is the most important reservoir for both resistance mechanisms and gene transfer in biological science studies. This study gives a bibliometric overview of studies of "antibiotic resistance" and "Escherichia coli" in the field of "Agricultural and Biological Sciences" from 2015 to 2019 to assess both research trends and scholarly networks in diverse research disciplines. The two keywords of "antibiotic resistance" and "Escherichia coli" were selected to search in the Scopus database. Each review article was categorized into materials, natural waters (i.e., seawater, freshwater) and wastewater, journal name, and quartile in category of the journal, the year of publication, and the country. Bibliometric indicators and visualization maps were utilized to analyse the retrieved data quantitatively and qualitatively. A total of 1376 publications in the field of agricultural and biological sciences over the last 5 years were obtained using the keywords of antibiotic resistance and Escherichia coli. With additional keywords of freshwater and wastewater, 4 and 24 studies were obtained, respectively. Wastewater was found to be the most common working environment for the keywords of antibiotic resistance and Escherichia coli. It is also found that the studies of antibiotic resistance are mainly conducted in wastewater environments, focusing on human and food health. Working under "One Health" consisting of human, animal and agriculture, and environmental health could be the only permanent and effective approach to solving antibiotic resistance-related issues.

Microplastic contamination in surface waters of the Küçükçekmece Lagoon, Marmara Sea (Turkey): Sources and areal distribution.

The distribution of freshwater and marine microplastics (MPs) varies due to the difference in fresh and seawater densities and MP sources. This study aims to investigate the abundance of MPs and their possible sources in surface waters of different ecosystems, such as sea, lagoon, and lake. We classified MPs in terms of their color and type and established the relationship between the MPs in surface waters with different characteristics. The mean MP abundance (33 particles L-1) detected herein was higher than that in the previously conducted studies. Fragment particles (37.95%) were determined to be the dominant MP type, and the predominant MP color was blue (75.28%). As for the seasonal MP distribution, its highest content (48.03 particles L-1) was observed in autumn, unlike that reported by other studies. The findings of this study reveal the effects of wastewater treatment plant (WWTP) discharge and current flow on the MP distribution in the study area. This study aims to provide representative data on the MP abundance and distribution, as well as MP-affecting parameters for similar aquatic areas in other parts of the world.

An alternative material for an effective treatment technique proposal in the light of bibliometric profile of global scientific research on antibiotic resistance and Escherichia coli.

Antibiotic resistance is considered by the countries to be a global health issue and a huge threat to public health. The reduction of resistant microorganisms from water/wastewater is of importance in environmental sciences since they are resistant in the aquatic environment. In this study, a bibliometric analysis of literature from the field of environmental science in water ecosystems from 2015 to 2019 was carried out using the keywords "Antibiotic Resistance (AR)" and "Escherichia coli". Furthermore, using the keywords of "Fresh Water," "Sea Water," and "Waste Water," 155, 52, and 57 studies were discovered, respectively. It is found that 217 studies of the total 2115 studies investigated on AR are mostly performed in the "Waste Water" by considering human health. Given the studies, an up-to-date solution should be proposed since the release of antibiotic-resistant bacteria (ARB) and antibiotic resistance genes (ARGs) from wastewater treatment plants needs to be mitigated. For this reason, it is obvious that working on micro and macro ecosystems will increase the probability of solutions in antibiotic resistance. A discussion of removal techniques for coliform bacteria, particularly antibiotic resistant Escherichia coli, was presented. One of the unique values of this study is to offer an innovative solution that removing them by metal-organic frameworks (MOFs) are emerging crystalline hybrid materials. MOFs are used for environmental, biological, and food antimicrobial substances efficiently. Therefore, we can give inspiration to the future studies of antimicrobial resistance removal via adsorption using MOFs as adsorbents. Graphical Abstract.

Potential threat of plastic waste during the navigation of ships through the Turkish straits.

The Turkish Straits System (TSS) is a dangerous and narrow waterway extending between the Black Sea and the Aegean Sea, including the Bosphorus, the Dardanelles, and the Marmara Sea and the Gulf of Izmit. The western banks of the TSS constitute the geographic starting point of the European continent, while the banks to the east are the beginnings of the Asia. TSS is considered one of the most strategically significant waterways of the world. This waterway is the main trading routes linking the Black Sea riparian countries to the world markets. As a result, the density in marine traffic through the TSS has recently reached alarmingly high levels. The aim of this study was to estimate the amount of plastic waste generated aboard merchant ships during their passage through the TSS during the period 2006-2017. This potential resource of waste would potentially impact on the Marmara Sea and its natural environment. The results of this study revealed that merchant ships crossing the TSS generated an average of 187.6 m3 of plastic waste per year. This result suggests that the threat given by the ships crossing this strait is approximately 1% of the total amount of waste recorded in the TSS coastals.

GIS based evaluation of social determinants of children's health in Turkey: Case study of Istanbul.

Basic elements considered as social determinants of the health varies in political, socio-economic, structural and intermediary contexts. While socio-economic and political contexts are directly related with the social, economic, public and health policies in country scale. The structural context additionally includes socio-economic dimensions such as income, education, occupation, social class, gender and race/ethnicity. In addition to these basic determinants, the public health, and especially the children health is also affected by the intermediary determinants, which are material circumstances including physical conditions of the working, housing and neighborhood environments and consumption potential (i.e. healthy foods, proper clothing etc.). Existing experiences provided that, the children who grow up on low socioeconomic conditions or on inappropriate environmental conditions including the residential structures tend to become more often ill than the children living in better environmental and socio-economic conditions. This situation reveals the importance of the city planning in terms of providing better conditions for children's health. This study aims to evaluate the social determinants of children's health by the use of Geographic Information System (GIS) technology. For this purpose, a variety of social determinants in terms of political (quality and quantity of health services), structural (education and social class) and intermediary (physical environment, housing, and neighborhood) contexts were examined in Bakirköy and Esenler districts, which are located European side of Istanbul. For this purpose, 2017 dated official dataset including census information and the statistics on the quality and the quantity of the education and health services in two districts were used for examining the political and structural determinants. The spatial characteristics of the physical environment and housing conditions in the study area were constructed from cadastral maps and development plans by use of GIS tools. As a last step, children's health data that consists of pediatric patient visits and diagnosis reports from 12 hospitals in Bakirköy and Esenler districts were also examined for understanding the potential relationships between the social determinants and existing health conditions. Results of this research revealed that the Bakirköy district has better conditions in terms of all health determinants when compared with Esenler district. Therefore, the health status of children living in Bakirköy is expected to be better than those living in the Esenler, which coincides with the evaluation of official children health data.

Freshwater plastic pollution: Recognizing research biases and identifying knowledge gaps.

The overwhelming majority of research conducted to date on plastic pollution (all size fractions) has focused on marine ecosystems. In comparison, only a few studies provide evidence for the presence of plastic debris in freshwater environments. However, owing to the numerous differences between freshwater studies (including studied species and habitats, geographical locations, social and economic contexts, the type of data obtained and also the broad range of purposes), they show only fragments of the overall picture of freshwater plastic pollution. This highlights the lack of a holistic vision and evidences several knowledge gaps and data biases. Through a bibliometric analysis we identified such knowledge gaps, inconsistencies and survey trends of plastic pollution research within freshwater ecosystems. We conclude that there is a continued need to increase the field-data bases about plastics (all size fractions) in freshwater environments. This is particularly important to estimate river plastic emissions to the world's oceans. Accordingly, data about macroplastics from most polluted and larger rivers are very scarce, although macroplastics represent a huge input in terms of plastics weight. In addition, submerged macroplastics may play an important role in transporting mismanaged plastic waste, however almost no studies exist. Although many of the most plastic polluted rivers are in Asia, only 14% of the reviewed studies were carried out in this continent (even though the major inland fisheries of the world are located in Asia's rivers). The potential damage caused by macroplastics on a wide range of freshwater fauna is as yet undetermined, even though negative impacts have been well documented in similar marine species. We also noted a clear supremacy of microplastic studies over macroplastic ones, even though there is no reason to assume that freshwater ecosystems remain unaffected by macro-debris. Finally, we recommend focusing monitoring efforts in most polluted rivers worldwide, but particularly in countries with rapid economic development and poor waste management.

Class 1 and class 2 integrons and plasmid-mediated antibiotic resistance in coliforms isolated from ten rivers in northern Turkey.

We aimed to determine the molecular mechanisms of antibiotic resistance in coliforms isolated from ten rivers in northern region of Turkey. A total of 183 isolates were tested for antimicrobial susceptibility by disk diffusion and agar dilution methods. Resistance to ampicillin, streptomycin, trimethoprim, tetracycline, and chloramphenicol was detected in 58%, 51.9%, 24%, 28.4%, and 12.5%, respectively. Twelve (6.5%) phylogenetically distant organisms were detected to harbor self-transmissible plasmids ranging 52 to >147 kb in sizes. Resistances to ampicillin, tetracycline, trimethoprim, streptomycin, and nalidixic acid were commonly transferable traits. Transferable nalidixic acid-resistant strains harbored qnrS gene, which was the first report of plasmid-mediated quinolone resistance in bacteria of environmental origin in Turkey. Fourteen and five coliforms harbored class 1 and class 2 integrons, respectively, and some of them were located on transferable plasmids. Sequence analyses of variable regions of the class 1 and 2 integrons harbored various gene cassettes, dfrA1, dfr2d, dfrA7, dfrA16, dfrA17, aadA1, aadA5, bla(oxA-30), and sat1. A gene cassette array, dfrA16 has been demonstrated for the first time in a Citrobacter koseri isolate. Class 1 and class 2-bearing strains were clustered in different groups by BOX-PCR fingerprinting. Rivers in the northern Turkey may act as receptacle for the multi-drug resistant enterobacteria and can serve as reservoirs of the antimicrobial resistance determinants in the environment. The actual risk to public health is the transfer of resistance genes from the environmental bacteria to human pathogens.

Estimation of stream temperature in firtina creek (Rize-Turkiye) using artificial neural network model.

Water temperature is one of the most important environmental variables in aquatic ecosystem. Temperature changes may have positive or negative effects on organisms. High water temperatures have caused mortalities in salmonid fishes. Therefore, monitoring and prediction of potential adverse changes in water temperature is very important. Here, we have developed and tested an artificial neural network (ANN) model to predict stream temperature of Firtina Creekin Black Sea region; using local water temperature, dissolved oxygen, pH and other available meteorological data (air temperature, rainfall). Thus, enabling define suitable habitat for native Sea Trout (Salmo trutta labrax, Pallas 1811) under past drought or other adverse envIronmental conditions.